2004
2005
2006
2007
2008

Publications


2005

Helix Architecture and Helicity Switching via Dynamic Metal Coordination Chemistry.
Hiroyuki Miyake and Hiroshi Tsukube
Supramolecular Chemistry,17, 53-59 (2005).

Molecular Recognition and Sensing via Rare Earth Complexes.
Satoshi Shinoda, Hiroyuki Miyake and Hiroshi Tsukube
Handbook on the Physics and Chemistry of Rare Earths, 35, Chapter 226, 2005,
(eds.) K. A. Gschneidner, Jr., J.-C. Bünzli, and V. Pecharsky, (Elsevier, Amsterdam).

Synthesis and Crystal Structures of [W(3,6-dichloro-1,2-benzenedithiolate)3]n-"n = 1, 2) and [Mo(3,6-dichloro-1,2-benzenedithiolate)3]2-: Dependence of the Coordination Geometry on the Oxidation Number and Counter-Cation in Trigonal-Prismatic and Octahedral Structures
Hideki Sugimoto, Yuuki Furukawa, Makoto Tarumizu,Hiroyuki Miyake, Koji Tanaka and Hiroshi Tsukube
Eur. J. Inorg. Chem., 3088-3092 (2005).

Dynamic Helicity Inversion in an Octahedral Cobalt(II) Complex System via Solvato-Diastereomerism.
Hiroyuki Miyake, Hideki Sugimoto, Hitoshi Tamiaki and Hiroshi Tsukube
Chem. Commun., 4291-4293 (2005).

A New Series of Molybdenum -(IV), -(V), and -(VI) Dithiolate Complexes as Active Site Models of Molybdoenzymes: Preparation, Crystal Structures, Spectroscopic / Electrochemical Properties, and Reactivity in Oxygen Atom Transfer
Hideki Sugimoto, Makoto Tarumizu, Koji Tanaka, Hiroyuki Miyake and Hiroshi Tsukube
Dalton Trans, 3558-3565 (2005).

Dioxo-Molybdenum(VI) and Mono-oxo-Molybdenum(IV) Complexes Supported by New Aliphatic Dithiolene Ligands: New Models with Weakened Mo=O Bond Characters for the Arsenite Oxidase Active Site.
Hideki Sugimoto, Makoto Harihara, Motoo Shiro, Kunihisa Sugimoto, Koji Tanaka, Hiroyuki Miyake and Hiroshi Tsukube
Inorg. Chem., 44, 6386-6392 (2005).

Mononuclear Five-Coordinate Molybdenum(IV) and -(V) Monosulfide Complexes Coordinated with Dithiolene Ligands: Reversible Redox of Mo(V)/Mo(IV) and Irreversible Dimerization of [MoVS]- Cores to a Dinuclear [MoV2(m-S)2]2- Core.
Hideki Sugimoto, Takashi Sakurai, Hiroyuki Miyake, Koji Tanaka and H. Tsukube,
Inorg. Chem.,44, 6927-6929 (2005).

らせん構造の構築と反転スイッチング:置換活性な金属錯体の特性を活用した新しいアプローチ (Helicity Induction and Switching: New Approach Using Labile Transition Metal Complexes)
三宅弘之
Bull. Jpn. Soc. Coord. Chem., 46, 11-14 (2005).(錯体化学会研究奨励賞受賞レビュー)

Cytochrome c – Crown Ether Complexes as Supramolecular Catalysts: Cold-Active Synzymes for Asymmetric Sulfoxide Oxidation in Methanol
Atsuko Suzumura, Dharam Paul, Hideki Sugimoto, Satoshi Shinoda, Ryan R. Julian, J. L. Beauchamp, Junji Teraoka, and Hiroshi Tsukube
Inorg. Chem., 44, 904-910 (2005).