Publication

Review Article

Original Article

2019

  • Iridium-Catalyzed Asymmetric Hydroarylation of Chromene Derivatives with Aromatic Ketones: Enantioselective Synthesis of 2-Arylchromanes
    Kana Sakamoto and Takahiro Nishimura*
    Adv. Synth. Catal. 2019, 361, 2124–2128. Selected as a "VIP" with Inside Cover Picture.
    DOI:10.1002/adsc.201801664
  • Iridium-Catalyzed Direct Hydroarylation of Glycals via C–H Activation: Ligand-Controlled Stereoselective Synthesis of α- and β-C-Glycosyl Arenes
    Kana Sakamoto, Masaki Nagai, Yusuke Ebe, Hideki Yorimitsu, and Takahiro Nishimura*
    ACS Catal. 2019, 9, 1374–1352.
    DOI:10.1021/acscatal.8b04686

2018

  • Iridium-Catalyzed Sequential sp3 C–H Alkylation of an N-Methyl Group with Alkenes Towards the Synthesis of α-Substituted Amines
    Hiroshi Hattori and Takahiro Nishimura*
    Adv. Synth. Catal. 2018, 360, 4827–4831.
    DOI:10.1002/adsc.201801131
  • Hydroxoiridium-Catalyzed sp3 C−H Alkylation of Indoline Derivatives with Terminal Alkenes
    Ikumi Nakamura, Daisuke Yamauchi, and Takahiro Nishimura*
    Asian J. Org. Chem. 2018, 7, 1347–1350.
    DOI:10.1002/ajoc.201800189
  • Stereocontrolled Synthesis of 19’-Deoxyperidinin
    Naoto Kinashi, Shigeo Katsumura,* Tetsuro Shinada, and Kazuhiko Sakaguchi*
    Org. Lett. 2018, 20, 582–585.
    DOI:10.1021/acs.orglett.7b03695
  • Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates
    Midori Nagamoto, Hideki Yorimitsu, and Takahiro Nishimura*
    Org. Lett. 2018, 20, 828–831.
    DOI:10.1021/acs.orglett.7b03969
  • Iridium/Chiral Diene-Catalyzed Enantioselective (3 + 2) Annulation of Aromatic Ketimines with 1,3-Enynes
    Midori Nagamoto, Kana Sakamoto, and Takahiro Nishimura*
    Adv. Synth. Catal. 2018, 360, 791–795.
    DOI:10.1002/adsc.201701378

2017

  • Stereocontrolled Synthesis of Paracentrone
    Yuto Nishioka, Yo Yano, Naoto Kinashi, Natsumi Oku, Youhei Toriyama, Shigeo Katsumura,* Tetsuro Shinada, Kazuhiko Sakaguchi*
    Synlett 2017, 28, 327-332.
    DOI: 10.1055/s-0036-1588906
  • Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides
    Midori Nagamoto, Jun-ichi Fukuda, Miyuki Hatano, Hideki Yorimitsu, and Takahiro Nishimura*
    Org. Lett. 2017, 19, 5952−5955.
    DOI: 10.1021/acs.orglett.7b02950
  • Iridium-Catalyzed Intramolecular Oxidative Cyclization of Alkenyl Amides and Alkenoic Acids
    Midori Nagamoto, Takahiro Nishimura,* and Hideki Yorimitsu
    Synthesis 2017, 49, 4272–4282.
    DOI: 10.1055/s-0036-1588435
  • Iridium-catalyzed sp3 C–H Alkylation of 3-Carbonyl-2-(alkylamino)pyridines with Alkenes
    Masaki Nagai, Midori Nagamoto, Takahiro Nishimura,* and Hideki Yorimitsu
    Chem. Lett. 2017, 46, 1176–1178.
    DOI: 10.1246/cl.170373
  • Iridium-catalyzed Cleavage of C–O Bonds Using Alcohols as Reducing Reagents
    Yuta Hibe, Yusuke Ebe, Takahiro Nishimura,* and Hideki Yorimitsu
    Chem. Lett. 2017, 46, 953–955.
    DOI: 10.1246/cl.170239
  • Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3)–H Bond Activation
    Daisuke Yamauchi, Takahiro Nishimura,* and Hideki Yorimitsu
    Angew. Chem., Int. Ed. 2017, 56, 7200–7204.
    DOI: 10.1002/anie.201702169
  • Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization
    Yusuke Ebe, Mitsuki Onoda, Takahiro Nishimura,* and Hideki Yorimitsu
    Angew. Chem., Int. Ed. 2017, 56, 5607–5611.
    DOI: 10.1002/anie.201702286
  • Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups
    Daisuke Yamauchi, Takahiro Nishimura,* and Hideki Yorimitsu
    Chem. Commun. 2017, 53, 2760–2763.
    DOI: 10.1039/c7cc00238f
  • Regularized Regression Analysis of Digitized Molecular Structures in Organic Reactions for Quantification of Steric Effects
    Shigeru Yamaguchi,* Takahiro Nishimura, Yuta Hibe, Masaki Nagai, Hirofumi Sato, and Ian Johnston
    J. Comput. Chem. 2017, 38, 1825–1833.
    DOI: 10.1002/jcc.24791

2016

  • Preparation of E-α-Stannyl-β-trimethylsilylethynylacrylate, Building Block for Polyconjugated Ylidenebutenolide and Its Derivatives, by Novel E-Selective Ethynylstannylation of Propiolate
    Naoto Kinashi, Kazuhiko Sakaguchi,* Shigeo Katsumura,* Tetsuro Shinada
    Tetrahedron Lett. 2016, 57, 129-132.
    DOI: 10.1016/j.tetlet.2015.11.079
  • Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes
    Midori Nagamoto, Tomoyuki Yanagi,Takahiro Nishimura,* and Hideki Yorimitsu
    Org. Lett. 2016, 18, 4474−4477.
    DOI: 10.1021/acs.orglett.6b01954
  • Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed by an Iridium Complex
    Miyuki Hatano, Takahiro Nishimura,* and Hideki Yorimitsu
    Org. Lett. 2016, 18, 3674−3677.
    DOI: 10.1021/acs.orglett.6b01721
  • Iridium-catalyzed asymmetric [3+2] annulation of aromatic ketimines with alkynes via C–H activation: unexpected inversion of the enantioselectivity induced by protic acids
    Midori Nagamoto, Daisuke Yamauchi, and Takahiro Nishimura*
    Chem. Commun. 2016, 52, 5876–5879.
    DOI: 10.1039/c6cc01398h
    Highlighted in Synfacts, Synfacts 2016, 12, 597.
  • Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C−H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes
    Miyuki Hatano, Yusuke Ebe, Takahiro Nishimura,* and Hideki Yorimitsu
    J. Am. Chem. Soc. 2016, 138, 4010−4013.
    DOI: 10.1021/jacs.6b01591
    Highlighted in Synfacts, Synfacts 2016, 12, 596.
  • Rhodium-Catalyzed Enantioselective Addition of Tricyclopropylboroxin to N-Sulfonylimines
    Takahiro Nishimura,* Tomotaka Nagai, Ryosuke Takechi, Yusuke Ebe
    Synthesis 2016, 48, 2612–2618.
    DOI: 10.1055/s-0035-1561605
    Highlighted in Synfacts, Synfacts 2016, 12, 699.

2015

  • Stereoselective hydroacylation of bicyclic alkenes with 2-hydroxybenzaldehydes catalyzed by hydroxoiridium/diene complexes
    Midori Nagamoto and Takahiro Nishimura*
    Chem. Commun. 2015, 51, 13791–13794.
    DOI: 10.1039/C5CC05432J
    Highlighted in Synfacts, Synfacts 2015, 11, 1064.
  • Iridium-catalyzed asymmetric cyclization of alkenoic acids leading to γ-lactones
    Midori Nagamoto and Takahiro Nishimura*
    Chem. Commun. 2015, 51, 13466–13469.
    DOI: 10.1039/C5CC05393E
    Highlighted in Synfacts, Synfacts 2016, 12, 64.
  • Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Imino-carboxamides with 1,3-Dienes
    Miyuki Hatano and Takahiro Nishimura*
    Angew. Chem., Int. Ed. 2015, 54, 10949–10952.
    DOI: 10.1002/anie.201505382
  • Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes
    Takahiro Sawano, Minoru Hashizume, Shouta Nishimoto, Keiyu Ou, and Takahiro Nishimura*
    Org. Lett. 2015, 17, 2630–2633.
    DOI: 10.1021/acs.orglett.5b00984
  • Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C–H Bond Activation
    Yusuke Ebe and Takahiro Nishimura*
    J. Am. Chem. Soc. 2015, 137, 5899−5902.
    DOI: 10.1021/jacs.5b03099
    Highlighted in Synfacts, Synfacts 2015, 11, 723.
  • Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes
    Ryosuke Takechi and Takahiro Nishimura*
    Chem. Commun. 2015, 51, 8528–8531.
    DOI: 10.1039/c5cc02140e
    Highlighted in Synfacts, Synfacts 2015, 11, 747.
  • Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of α,α-diaryl-α-amino acid derivatives
    Ryosuke Takechi and Takahiro Nishimura*
    Org. Biomol. Chem. 2015, 13, 4918–4924.
    DOI: 10.1039/c5ob00431d
  • Iridium-Catalyzed Annulation of Aromatic Imines with 1,3-Dienes via Direct Functionalization of an Aromatic C–H Bond
    Yusuke Ebe, Miyuki Hatano, and Takahiro Nishimura*
    Adv. Synth. Catal. 2015, 357, 1425–1436. (VIP)
    DOI: 10.1002/adsc.201401171

2014

  • Straightforward synthesis of fucoxanthin short-chain derivatives via modified-Julia olefination
    Satoshi Okumura, Takayuki Kajikawa, Koki Yano, Kazuhiko Sakaguchi, Daisuke Kosumi, Hideki Hashimoto, Shigeo Katsumura*
    Tetrahedron Lett. 2014, 55,, 407-410.
    DOI: 10.1016/j.tetlet.2013.11.043
  • Iridium-Catalyzed Annulation of Salicylimines with 1,3-Dienes
    Yusuke Ebe and Takahiro Nishimura*
    J. Am. Chem. Soc. 2014, 136, 9284–9287.
    DOI: 10.1021/ja504990a
    Highlighted in Synfacts as Synfact of the month, Synfacts 2014, 10, 931.
  • Catalytic [3 + 2] annulation of ketimines with alkynes via C–H activation by a cationic iridium(cod) complex
    Midori Nagamoto and Takahiro Nishimura*
    Chem. Commun. 2014, 50, 6274–6277.
    DOI: 10.1039/C4CC01874E

2013

  • Enantioselective [3 + 2] annulation via C–H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes
    Takahiro Nishimura,* Midori Nagamoto, Yusuke Ebe, and Tamio Hayashi
    Chem. Sci. 2013, 4, 4499–4504.
    DOI: 10.1039/c3sc52379a
    Highlighted in Synfacts as Synfact of the month, Synfacts 2014, 10, 157.
  • Cobalt-Catalyzed Asymmetric Addition of Silylacetylenes to 1,1-Disubstituted Allenes
    Takahiro Sawano, Keiyu Ou, Takahiro Nishimura,* and Tamio Hayashi
    J. Org. Chem. 2013, 78, 8986−8993. [Featured Article]
    DOI: 10.1021/jo401604n
    Highlighted in Synfacts, Synfacts 2013, 8, 1321.
  • Asymmetric Synthesis of gem-Diaryl Substituted Cyclic Sulfamidates and Sufamides by Rhodium-Catalyzed Arylation of Cyclic Ketimines
    Takahiro Nishimura,* Yusuke Ebe, Hiroto Fujimoto, and Tamio Hayashi
    Chem. Commun. 2013, 49, 5504–5506.
    DOI: 10.1039/C3CC42071J
  • Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides
    Takahiro Nishimura,* Yuka Takiguchi, Yuko Maeda, and Tamio Hayashi*
    Adv. Synth. Catal. 2013, 355, 1374–1382.
    DOI: 10.1002/adsc.201300148
  • Iridium-Catalyzed [3+2] Annulation of Cyclic N-Sulfonyl Ketimines with 1,3-Dienes via C-H Activation
    Takahiro Nishimura,* Yusuke Ebe, and Tamio Hayashi
    J. Am. Chem. Soc. 2013, 135, 2092–2095.
    DOI: 10.1021/ja311968d
    Highlighted in Synfacts as Synfact of the month, Synfacts 2013, 9, 503.
  • Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3-Aryl-3-hydroxyisoindolin-1-ones
    Takahiro Nishimura,* Akira Noishiki, Yusuke Ebe, and Tamio Hayashi*
    Angew. Chem., Int. Ed. 2013, 52, 1777–1780.
    DOI: 10.1002/anie201208593
    Highlighted in Synfacts, Synfacts 2013, 9, 401.

2012年以前は、コチラ(cv,publication list)をご参照ください。

大阪市立大学 理学研究科・理学部
物質分子系専攻・化学科
精密有機化学研究室

Fine Organic Chemistry Laboratory
The Nishimura Group
Department of Chemistry,
Graduate School of Science,
Osaka City University
3-3-138 Sugimoto Sumiyoshi-ku,
Osaka 558-8585, Japan

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Fine Organic Chemistry Laboratory
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